In a small bowl, whisk together the balsamic vinegar, honey, garlic powder, salt, and pepper until combined.
Arrange the pork chops in a single layer at the bottom of your slow cooker.
Pour the balsamic honey mixture evenly over the pork chops.
Cover the slow cooker and cook. For firm, sliceable chops, cook on HIGH for 1.5 to 2 hours. For very tender, shreddable pork, cook on LOW for 5 to 6 hours.
Check for doneness by inserting a meat thermometer into the thickest part of a pork chop. It should read at least 145°F (63°C).
Remove the pork chops from the slow cooker and transfer them to a plate. Let them rest for at least 3 minutes before serving.
Optional: For a thicker sauce, pour the remaining liquid from the crockpot into a small saucepan. Bring to a simmer over medium heat and cook for 3-5 minutes, or until it has reduced and thickened slightly.
Spoon the sauce over the rested pork chops and serve.